206996-60-3, Name is Cerium(III) acetate xhydrate, molecular formula is C6H11CeO7, belongs to catalyst-ligand compound, is a common compound. In a patnet, author is Liu, Chenguang, once mentioned the new application about 206996-60-3, Product Details of 206996-60-3.
Manganese-Catalyzed Asymmetric Hydrogenation of Quinolines Enabled by pi-pi Interaction
The non-noble metal-catalyzed asymmetric hydrogenation of N-heteroaromatics, quinolines, is reported. A new chiral pincer manganese catalyst showed outstanding catalytic activity in the asymmetric hydrogenation of quinolines, affording high yields and enantioselectivities (up to 97 % ee). A turnover number of 3840 was reached at a low catalyst loading (S/C=4000), which is competitive with the activity of most effective noble metal catalysts for this reaction. The precise regulation of the enantioselectivity were ensured by a pi-pi interaction.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI