Reference of 1271-19-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1271-19-8, Name is Titanocenedichloride, molecular formula is C10Cl2Ti. In a Article，once mentioned of 1271-19-8
Treatment of cyclotrisilathiane (Me2SiS)3 with 3 equiv. of RLi (R = Me, But) in hexane-Et2O afforded the lithium silanethiolates LiSSiMe2R, and the tmeda adduct [(tmeda)LiSSiMe2But]2 1(tmeda = N,N,N?,N?-tetramethylethylenediamine) was isolated in the case of R = But. Reaction of Fe(CH3CN)2(CF 3SO3)2, CoCl2, and [Cu(CH 3CN)4](PF6) with 1 gave rise to the silanethiolato complexes M(SSiMe2But)2(tmeda) (M = Fe 2, Co 3), and [Cu(SSiMe2But)]4 4, respectively. Complexes (C5H5)2Ti(SSiMe 2R)2 (R = Me 5, But 6) and Ni(SSiMe 2R)2(dppe) [R = Me 7, But 8; dppe = 1,2-bis(diphenylphosphino)ethane] were prepared from treatments of (C 5H5)2TiCl2 and NiCl 2(dppe) with the corresponding lithium silanethiolates. Complex 7 readily reacted with (C5H5)TiCl3 to produce the Ti-Ni heterobimetallic compound (C5H5)TiCl(mu-S) 2Ni(dppe) 9, in which silicon-sulfur bond cleavage took place. Characterization of all compounds through spectroscopic techniques and elemental analyses are also described. X-Ray structural data for compounds 1 and 3-9 are reported.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI