Top Picks: new discover of (1S,2S)-(-)-1,2-Diphenylethylenediamine

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 29841-69-8

Synthetic Route of 29841-69-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.29841-69-8, Name is (1S,2S)-(-)-1,2-Diphenylethylenediamine, molecular formula is C14H16N2. In a Article,once mentioned of 29841-69-8

Two copper(II)-gadolinium(III) metal complexes of formula Cu IIGdIIILX3 are reported. H2L stands for the Schiff base ligand obtained by condensation of 3,4- dimethoxysalicylaldehyde with ethylenediamine (complex 1) or 1R,2R-(+)-1,2-diphenylethylenediamine (complex 2). While 1 reveals a centrosymmetric crystal structure, 2 crystallizes in the noncentrosymmetric P212121 space group and exhibits an efficiency 0.3 time that of urea in second harmonic generation. Due to a trend for dissociation in solution, the molecular hyperpolarizabilities (beta) cannot be determined experimentally for 1 and 2. Nevertheless, the electric field induced second harmonic (EFISH) technique, in connection with spectroscopic data and a ZINDO semiempirical approach, leads to a beta value of -6.5 × 10 -30 cm5 esu1, for the related Cu11L monomers, as an indicative range of magnitude in all these Schiff base complexes. In addition, 1 and 2 exhibit a ferromagnetic coupling in solid state with J = 3.3 and 1.3 cm-1, respectively (J being the parameter of the exchange Hamiltonian H = -JSCu·SGd).

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 29841-69-8

Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI