Application of 1271-19-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1271-19-8, Name is Titanocenedichloride, molecular formula is C10Cl2Ti. In a Article,once mentioned of 1271-19-8
Bimetallic titanium and zirconium complexes with bridges (X) between Cp ligands were compared to Cp2MCl2 as catalysts in the presence of nBuLi for the dehydrocoupling of PhSiH3 to polyphenylsilane. The monobridged bimetallic complexes developed were of the composition [ mu-X(C5H4)2ICpMCl2]2 with X = Me2Si (M = Ti, Zr), Me2SiCH2SiMe2 (M = Ti) and Me2SiCH2CH2SiMe2 (M – Ti, Zr). The dibridged bimetallic complexes examined were of the type [mu,mu-(Me2Si)2(C5H3)2ICp?TiCl2l2 (Cp? = Cp, trans isomer, Cp? = Cp *, trans and cis isomers). There was not a significant difference in the molecular weight of the polysilane produced from Cp2TiCl2 and the bimetallic titanium complexes after 48 h of reaction. However, the polysilane which was generated from the bimetallic complex [ mu-(Me2Si)(C5H4)2ICpZrCl2]2 was approximately twice the molecular weight compared to that obtained from Cp2ZrCl2. The structure of the bimetallic complex [ mu-(Me2SiCH2CH2SiMe2)(C5H4)2ICpZiCl2]2 was determined by X-ray diffraction (monoclinic, P21/n, a = 8.7297(3)A, b = 6.7890(2)A, c = 24.9343(7)A, beta = 93.7850(10), Z=2).
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1271-19-8
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI