Reference of 18531-94-7, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.18531-94-7, Name is (R)-[1,1′-Binaphthalene]-2,2′-diol, molecular formula is C20H14O2. In a Article£¬once mentioned of 18531-94-7
Synthesis and enantiomeric recognition ability of 22-crown-6 ethers derived from rosin acid and BINOL
Four novel chiral 22-crown-6 ethers 6a-b, 7a-b bearing hydroxyl side groups derived from rosin acid and BINOL were prepared in optically pure forms, and their enantiodiscriminating abilities towards protonated primary amines and amino acid methyl ester salts were examined by UV-vis titration methods. These receptors exhibited good chiral recognition towards the isomers (up to K D/KL = 6.02, DeltaDeltaG0 = 4.45 kJ mol-1) and showed different complementarity to various chiral guests.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI