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Effects of Fe, Ti, and v doping on the microstructure and electrical properties of grain and grain boundary of giant dielectric NiO-based ceramics
We report the giant dielectric response and electrical properties of Li0.05 B0.02 Ni0.93 O (B=Fe, Ti, and V) ceramics prepared by a polymer pyrolysis route. The giant dielectric response in these materials can be ascribed based on the Maxwell-Wagner polarization and thermally activated mechanisms. It is found that Fe, Ti, and V doping has a strong effect on the microstructure and the conduction of grains and grain boundaries of these NiO-based ceramic systems, which make large contribution to their dielectric properties.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI