Some scientific research about 1271-19-8

Reference of 1271-19-8, Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. 1271-19-8, Name is Titanocenedichloride,introducing its new discovery.

REACTIONS OF SEMICARBAZONES WITH BIS(CYCLOPENTADIENYL)-TITANIUM(IV)CHLORIDE

The reactions of bis(cyclopentadienyl)titanium(IV)chloride (Cp2TiCl2) with mono- and dibasic semicarbazones in tetrahydrofuran (molar ratio 1:1) in the presence of triethylamine at room temperature, have been described.With monobasic semicarbazones (derived from condensation of semicarbazide with aldehydes/ketones) such as of acetone (AcScH), acetophenone (AcPhScH), benzophenone (BzPhScH), ethylmethylketone (EMScH), iso-butylmethylketone (i-BuMeScH), cyclopentanone (CyPScH), cyclohexanone (CyHxScH), furfuraldehyde (FScH), benzaldehyde (BAScH) and cinnamaldehyde (CinAScH), Cp2TiCl2 reacts with the formation of derivatives of the type where – is the anion of the corresponding monobasic semicarbazone.The reactions of Cp2TiCl2 with dibasic semicarbazones (derived from hydroxy aryl aldehydes) such as of salicylaldehyde (SASc’H2) and vanillin (VanSc’H2) yield the product of the type , where 2- is the anion of the corresponding dibasic semicarbazone.These complexes have been cheracterized on the basis of elemental analyses, electrical conductance measurements and spectral (infrared, NMR and electronic) data.

If you¡¯re interested in learning more about 287192-97-6, below is a message from the blog Manager. Reference of 1271-19-8

Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI