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LDA-induced halogen migrations and their selective preventions on various bromo substituted thiophenes and furans gave upon reaction with electrophiles access to a large variety of new tri-substituted derivatives.Extension of HD-methodology to 5,5′-dibromo-2,2′-bithiophene enabled for the first time control of selective mono- and double halogen migration.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI