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A symmetrical salen ligand is formed by the condensation of (1R,2R)-diaminocyclohexane with 4-hydroxy-3-phenanthrenecarboxaldehyde. Crystallographic characterization of the metal complexes (ZnII, FeII, and FeIII) show 1:1 mixtures of diastereomeric M and P helical molecules. ECD spectra of the ZnII complex combined with DFT simulations strongly suggest that the M conformation is dominant in solution. This is supported by 1H and 13C NMR data, which are consistent with a single species in solution.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI