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In this study we have examined the catalytic activity of vanadium(V) complexes such as left bracket VO(DBcat**)//2 right bracket ** minus and heteropolyvanadates for the purpose of comparison with the previous results. In particular, we have interested in oxygenation using heteropolyvanadates because these compounds have polynuclear structures with many oxyanions capable of oxidizing organic compounds. The authors discuss the reaction mechanism on the basis of the isolated complex which can be regarded as an intermediate of the reaction.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI