So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Huang, Fei; Zhang, Songlin researched the compound: 11-Bromoundecanoic acid( cas:2834-05-1 ).Recommanded Product: 11-Bromoundecanoic acid.They published the article 《Iminyl Radicals by Reductive Cleavage of N-O Bond in Oxime Ether Promoted by SmI2: A Straightforward Synthesis of Five-Membered Cyclic Imines》 about this compound( cas:2834-05-1 ) in Organic Letters. Keywords: oxime iminyl radical reductive bond cleavage cyclization samarium iodide; five membered cyclic imine preparation. We’ll tell you more about this compound (cas:2834-05-1).
A new generation method of N-centered radicals from the reductive cleavage of the N-O bond in oxime ether promoted by SmI2 is reported for the first time. The in-situ-generated N-centered radicals underwent intramol. cyclization to afford five-membered cyclic imines in two manners: N-centered radical addition and N-centered anion nucleophilic substitution. From a synthetic point of view, an efficient synthetic method of five-membered cyclic imines was developed. A mechanism of the transformation was proposed.
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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI