One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 1119-97-7, Name is MitMAB, formurla is C17H38BrN. In a document, author is Sang, Wei, introducing its new discovery. Formula: C17H38BrN.
Transition-Metal-Free Base-Controlled C-N Coupling Reactions: Selective Mono Versus Diarylation of Primary Amines with 2-Chlorobenzimidazoles
Herein, a base-controlled protocol was developed for the C-N coupling of primary amines and 2-chlorobenzimidazoles, affording a handful of secondary or tertiary amines in a selective fashion. Moreover, this protocol was realized under transition-metal-free conditions, and the variation of the base from iPr(2)NH to LiOtBu completely switched the selectivity from monoarylation to diarylation. Further investigations elucidated that the variety, intrinsic basicity and amount of the utilized bases considerably affected these reactions.
If you are hungry for even more, make sure to check my other article about 1119-97-7, Formula: C17H38BrN.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI