Related Products of 18531-94-7, In heterogeneous catalysis, the catalyst is in a different phase from the reactants. At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 18531-94-7, name is (R)-[1,1′-Binaphthalene]-2,2′-diol. In an article£¬Which mentioned a new discovery about 18531-94-7
Metal-directed stereoselective syntheses of homochiral complexes of exo-bidentate binaphthol derivatives
The homochiral exo-bidentate ligands (S)-2,2?- bis(pyridylmethyleneoxy)-1,1?-binaphthyl [(S)-L] and (R)-2,2?- bis(pyridylmethyleneoxy)-1,1?-binaphthyl [(R)-L] were synthesized and employed for the preparation of coordination complexes with the aim of investigating the effect of an axially chiral 1,1?-binaphthyl connector on self-assembly process. Five homochiral complexes, [Ag{(S)-L}(ClO 4)]n (1), [Ag{(R)-L}(ClO4)]n (2), [{Cd{(S)-L}(H2O)Cl2}(H2O)0.5] n (3), [(Zn{(S)-L}Cl2)(DMF)0.5(H 2O)0.5]n (4), and [(Pd2{(S)-L} 2Cl4)(H2O)1.5]n (5), have been prepared and characterized by single-crystal X-ray diffraction analyses. The enantiomeric complexes 1 and 2 are isomorphous and are formed through interconnection of ligands and two-coordinate AgI centers. Complex 3 possesses a similar structural framework to 1 and is formed with two nitrogen atoms from (S)-L coordinating to six-coordinate CdII in a trans mode. The interlocking in part of the adjacent, one-dimensional helix-like chains stabilizes its structure. Complex 4 is a one-dimensional zigzag chain and is formed through interconnection of (S)-L and ZnCl2 units. The exo-bidentate (S)-L ligand in 5 links square-planar PdII into a homochiral dinuclear metallomacrocycle. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.18531-94-7. In my other articles, you can also check out more blogs about 18531-94-7
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI