Reference of 1660-93-1, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1660-93-1, Name is 3,4,7,8-Tetramethyl-1,10-phenanthroline, molecular formula is C16H16N2. In a Article,once mentioned of 1660-93-1
Preparation of rod-shaped nanostructure of a new 1D lead(II) tri nuclear coordination polymer containing the Pb2-(mu-N3)2 and Pb2-(mu-N3)(NO3) motifs [Pb3(tmph)4(mu-N3)5(mu-NO3)]n (1) where “tmph” is the abbreviation of 3,4,7,8-tetramethyl-1,10-phenanthroline, using a sonochemical method is described. The new coordination polymer is characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), elemental analysis and infrared spectroscopy. The single crystalline material is obtained using a heat gradient applied to a solution of the reagents. Single-crystal XRD analysis indicates three different lead(II) centers in the structure with coordination numbers of seven and eight with a holo and hemidirected coordination geometry. They also show that the chains interact with each other through pi-pi stacking interactions creating a 3D framework. PbO nanoparticles are obtained by thermolysis of 1 at 180 C with oleic acid as a surfactant. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) confirm formation of PbO particles around 10-20 nm.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI