Extracurricular laboratory:new discovery of 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane

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Application of 41203-22-9, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.41203-22-9, Name is 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane, molecular formula is C14H32N4. In a Article£¬once mentioned of 41203-22-9

Electron-transfer Chemistry of the Luminescent Excited State of trans-Dioxo-osmium(VI)

Excitation of trans-dioxo-osmium(VI) complexes in the solid state and in fluid solutions at room temperature at 350-400 nm results in red emission with maxima at 620-710 nm.Rate constants for electron-transfer quenching of trans-2+. (L1 = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) and trans-2+. heptadeca-1(17),13,15-triene> by a series of structurally related aromatic hydrocarbons with varying redox potentials have been determined in acetonitrile.The3Eg states of trans-2+ and trans-2+ are powerful one-electron oxidants, the excited-state reduction potentials of which in acetonitrile, E0 (OsVI*-OsV), have been found to be 2.39(10) and 2.00(10) V vs. normal hydrogen electrode respectively, which agree well with estimations using spectroscopic and electrochemical data.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI