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Chiral selen-titanium complexes were found to be efficient catalysts for the enantioselective trimethylsilylcyanation of aldehydes. An enantioselectivity up to 87.1% e.e, was obtained by using 10mol% Ti(IV)-salen 2d as catalyst. The reaction mechanism was proposed and proved experimentally.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI