Discovery of (R)-[1,1′-Binaphthalene]-2,2′-diol

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An intramolecular SNAr reaction makes the synthesis of enantiopure MAP(O)-type P,N ligands in high yields possible (see scheme) and demonstrates that the synthetic potential of the 85-year-old Staudinger reaction between phosphanes and azides is still far from being exhausted. Nf = nonafluorobutanesulfonate.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI