Discovery of 5-Ethynyl-2,2′-bipyridine

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Three 4,5-diheteroarylphenanthrenes 2a, 2b and 2c and two dinuclear Ru(II) bis(terpyridine) complexes 13 and 14 possessing severe helical twists were synthesized. The Royal Society of Chemistry 2010.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI