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The interaction of a homologous series of n-alkyltrimethylammonium bromides (C8-C14 TABs) with hen egg lysozyme have been ivestigated using microcalorimetry.The C8 TAB does not interact with lysozyme whereas the C10-C14 TABs interact endothermically and deactivate the enzyme.The endothermicity of the TAB-lysozyme interaction is a marked contrast to the exothermic interactions between n-alkyl sulfates and lysozyme which have been attributed to specific binding between the anionic sulfate head groups and cationic amino acid residues.The enthalpies of interaction between the cationic surfactans and lysozyme follow sigmoidal curves characteristic of an interaction dominated by the endothermic unfolding of the native structure.The enthalpy data have been used to obtain the Gibbs energy and entropy for surfactant-induced denaturation.At pH 10 the Gibss energy, enthalpy and entropy of denaturation are 17.9 +/- 4.2 kJ mol-1, 148 +/- 15 kJ mol-1 and 436 J mol-1 K-1 at 25 deg C.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The palladium on alumina (Pd@Al2O3)-catalyzed hydrogenation of allylbenzene to propylbenzene was studied in methanol and aqueous micellar solutions of sodium dodecyl sulfate (SDS), decyltrimethylammonium bromide (DTAB), and t-octylphenoxypolyethoxyethanol (TX-100). Over Pd@Al2O3, propylbenzene was obtained via direct hydrogenation of allylbenzene and isomerization to beta-methylstyrene which was hydrogenated afterwards. In aqueous micellar solutions, the reaction was faster than in pure water, but slower than in methanol due to lower hydrogen solubility. In the H2O/SDS system, a higher activation energy was obtained than in methanol. For the investigated surfactants, the initial reaction rate in the micellar systems decreased in the order SDS >TX-100 >DTAB.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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A process of preparing nanostructured lithium titanate particles. The process contains the steps of providing a solvent containing a soft-template compound, a lithium ion-containing compound, and a titanium ion-containing compound; removing the solvent to obtain a lithium titanate precursor; and calcining the precursor followed by milling and annealing. Also disclosed is a nanostructured lithium titanate particle prepared by this process.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Quality Control of: N,N,N-Trimethyldecan-1-aminium bromide, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 2082-84-0, Name is N,N,N-Trimethyldecan-1-aminium bromide, molecular formula is C13H30BrN. In a Article, authors is Lee, E. M.,once mentioned of 2082-84-0

The technique of specular reflection of neutrons has been used to investigate the adsorption of decyltrimethylammonium bromide (DTAB) at the aqueous solution/air interface over the concentration range 0.002-0.1 M.Hydrogen-deuterium substitution in both surfactant and solvent has been used to highlight different features of the adsorbed layer and to distinguish between solvent and solute in this layer.At the lowest concentration the thickness of the adsorbed layer is 16+/-3 Angstroem, indicating that the molecules are aligned with the long axis perpendicular to the interface.At a concentration of 0.05 M, where the monolayer is essentially complete, the thickness is found to be 21+/-1 Angstroem.This suggests that in the more closely packed monolayer the head groups, which carry a positive charge, may be ”staggered” in order to minimize their mutual repulsion.A detailed analysis of the structure at 0.05 M indicates that the layer may be divided into two regions: a head group region, 6 Angstroem thick, containing the trimethylammonium head group, counterion, water, and about 10percent of the alkyl chain tails; and a tail group region 15 Angstroem thick, containing only tail groups.The area per molecule of surfactant at the saturated monolayer is found to be 58+/-5 Angstroem2.Above the critical micelle concentration (0.065 M) the structure of the interface is more complex.The monolayer itself is some 15percent more dense than the saturated monolayer formed below the cmc.The shape of the reflectivity profile is shown to be consistent with some ordering of the micelles beneath the surface, separated from the monolayer by a thin layer of water, which contains no surfactant and which has a density more akin to that of water in hydrates.Mixtures of DTAB and sodium decanoate have also been investigated.Equimixtures of the two oppositely charged surfactants are much more strongly adsorbed than either of the two individual components.Even at the low total concentration of 0.01 M the area per surfactant molecule of the mixed monolayer is 36 Angstroem2 compared with 73 Angstroem2 for 0.01 M DTAB alone.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Optical detection of triplet-state magnetic resonance (ODMR) is used to study the phosphorescent state of naphthalene (N) solubilized into trimethyl-n-alkylammonium bromide (C(n)TABR) micelles.The results are compared with those found for N solubilized by sodium n-alkyl sulfate (NaC(n)S) micelles.In NaC(n)S the 0,0 phosphorescence band of N shifts to the red and resolution increases with increasing n, indicating a progressively less polar environment.A similar trend is observed in C(n)TABR; for a given n, however, the N site is more polar in C(n)TABR.A trend in zero-field splitting (ZFS) parameter <*> observed in different micelles suggests that the polarizability increases in the sequence NaC10S < C10TABR = C12TABR = C14TABR = NaC12S < NaC14S < C16TABR.The triplet lifetime decreases linearly in C(n)TABR micelles with decreasing n and the normally unobserved <*>–<*>ODMR transition appears when n +<*> transition is independent of n in NaC(n)S, it increases with decreasing n in C(n)TABR because of an increase in heterogeneity of the N site.This effect could result from enhanced interactions with the cationic head groups of the surfactant and/or from increased water penetration into the cationic micelles.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The specific heat capacities of triethylene glycol monopentyl ether aqueous solutions have been measured from 278.15 to 338.15 K, over the wide concentration range by DSC. The apparent and partial molar heat capacities were calculated and the two-point scaling theory was used to analyze these data. Obtained results were discussed in terms of aggregation taking place in the solution and influence of the temperature on this process. The separation line between single-phase solution and two-phase system was determined using scanning calorimetry.

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Metal catalyst and ligand design,
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A very large number of different synthesis approaches for the preparation of mesoporous materials has been reported in literature since the first development of ordered mesoporous materials in the 1990’s. Since then, the synthesis of advanced mesoporous materials has undergone an explosive growth. Moreover, this type of materials gains growing success in a wide variety of applications. For these reasons and with the example of the book of verified microporous zeolite syntheses in mind, it is obvious that there is a growing need for verified synthesis methods of mesoporous materials. In this work, verified synthesis methods have been compiled for a large number of selected relevant structured mesoporous silica and titania materials as well as for some super-microporous materials (defined herein as materials with pore diameters between 1.5 and 2 nm). In addition, for each material, a basic set of material characteristics have been reported based on the most commonly applied characterization techniques (nitrogen sorption, XRD, TEM, SEM, NMR, etc.) for mesoporous materials.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The present invention relates to complexes formed from molecular encapsulation agents such as cyclodextrin, and cyclopropene and its derivatives such as methylcyclopropene, which are capable of inhibiting the ethylene response in plants. More specifically this invention relates to compositions of cyclopropenes and molecular encapsulation agents containing additives to improve the release of the cyclopropene when the composition is contacted with water.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Hollow nanomaterials have attracted a broad interest in multidisciplinary research due to their unique structure and preeminent properties. Owing to the high specific surface area, well-defined active site, delimited void space, and tunable mass transfer rate, hollow nanostructures can serve as excellent catalysts, supports, and reactors for a variety of catalytic applications, including photocatalysis, electrocatalysis, heterogeneous catalysis, homogeneous catalysis, etc. Based on state-of-the-art synthetic methods and characterization techniques, researchers focus on the purposeful functionalization of hollow nanomaterials for catalytic mechanism studies and intricate catalytic reactions. Herein, an overview of current reports with respect to the catalysis of functionalized hollow nanomaterials is given, and they are classified into five types of versatile strategies with a top-down perspective, including textual and composition modification, encapsulation, multishelled construction, anchored single atomic site, and surface molecular engineering. In the detailed case studies, the design and construction of hierarchical hollow catalysts are discussed. Moreover, since hollow structure offers more than two types of spatial-delimited sites, complicated catalytic reactions are elaborated. In summary, functionalized hollow nanomaterials provide an ideal model for the rational design and development of efficient catalysts.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Hydrogels and organogels are semi-solid systems, in which a liquid phase is immobilized by a three-dimensional network composed of self-assembled, intertwined polymer/gelator fibers. Investigations pertaining to these systems have only picked up speed in the last few decades. Consequently, many burning questions regarding these systems, such as the specific molecular requirements guaranteeing gelation, still await definite answers. Nonetheless, the application of different hydrogels and organogels to various areas of interest, i.e., as drug delivery devices, has been quick to follow their discoveries. The use of NMR spectroscopy for the characterization of polymer hydrogels and organogels has recently seen enormous growth. The NMR measurements involving magic angle spinning (MAS) in the solid-state NMR, spin relaxation times, nuclear Overhauser enhancements (NOE), or multiple-quantum (MQ) spectroscopy, the pulse field gradient (PFG) technique and magnetic resonance imaging (MRI) allow obtaining the detailed information on morphology, molecular organization, specific interactions and internal mobility of constituents. This review aims at providing a global view and capabilities all of these NMR methods in comprehensive studies of hydrogels and organogels, with special emphasis on the interplay between the morphology and molecular mobility of constituents and the intermolecular interactions.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI