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The synthetic zeolite Na-P1 and natural clinoptilolite are modified using dodecyl trimethyl ammonium bromide (DDTMA), didodecyl dimethyl ammonium bromide (DDDDMA), tetradecyl trimethyl ammonium bromide (TDTMA), ditetradecyl dimethyl ammonium bromide (DTDDMA), hexadecyl trimethyl ammonium bromide (HDTMA), dihexadecyl dimethyl ammonium bromide (DHDDMA), octadecyl trimethyl ammonium bromide (ODTMA) and dioctadecyl dimethyl ammonium bromide (DODDMA) in amounts of 1.0 of the external cation exchange capacity of the zeolites. The sorption performance of the zeolites and organo-zeolites for aqueous benzene, ethylbenzene, toluene, p-xylene (BTEX) and hexane are evaluated. After modification, the organo-zeolites show good performance for the removal of BTEX and hexane from the aqueous solution. The results show that the modification of the zeolites by surfactants with double-carbon chains (DDDDMA, DTDDMA, DHDDMA and DODDMA) improves the sorption properties for benzene, ethylbenzene and toluene. In the case of ethylbenzene, the sorption results are twice as high for the modified zeolites compared to the unmodified zeolites. Based on the experimental data, the removal efficiencies follow the order of hexane > ethylbenzene > toluene > p-xylene > benzene. Hexane was adsorbed in the greatest quantity on the zeolite (~75?80%) and all organo-zeolites (~90?95%). Benzene was adsorbed in the lowest quantity on the zeolite (40?50%) and the organo-zeolites (30?40%). Simultaneously, it is shown that the sorption efficiency increases with increasing carbon chain length. The sorption efficiency depends on the chemical properties of the various organic compounds and the duration of the sorption process.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Poly(3,4-ethylenedioxythiophene)/titanium dioxide (PEDOT/TiO2) nanocomposites and poly(3,4-ethylenedioxythiophene) (PEDOT) homopolymers were synthesized chemically in the presence of anionic (sodium dodecylsulfate, SDS) and cationic (tetradecyltrimethylammoniumbromide, TTAB) surfactants. The effect of surfactant on structural and morphological properties of the nanocomposites was investigated using UV-vis spectroscopy, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), four-probe conductivity measurements and X-ray photoelectron spectroscopy (XPS) measurements. It was observed from SEM study that the nanocomposites show globular particle structure with different particle size. The PEDOT/TiO2 nanocomposite has higher conductivity than that of pure PEDOT homopolymer. The presence of surfactant during PEDOT/TiO2 nanocomposites synthesis influenced thermal stability of the prepared samples.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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This study investigates the behavior of mixed protein/ionic surfactant mixtures in an aqueous/p-xylene system. Tritium labeled compounds and the scintillation phase method were used to study the competitive adsorption and distribution of lysozyme, sodium dodecyl sulfate (SDS, an anionic surfactant) and dodecyltrimethylammonium bromide (DTAB, a cationic surfactant) in the aqueous/p-xylene system. The substitution of lysozyme by both surfactants was observed, even when the concentration of the surfactants was only about 7×10-8mol/l, that is, four orders of magnitude below the surfactants’ critical micelle concentration (CMC). A radiochemical study indicated that both surfactants eject the lysozyme into the organic phase. The obtained experimental data were helpful in explaining the significant synergistic effect that was observed between lysozyme and DTAB at the aqueous/p-xylene interface. Based on the experimental data and calculations, a mechanism of the formation of lysozyme – ionic surfactants mixed adsorption layer at the aqueous/p-xylene interface was revealed. The experimental study was carried out for ionic surfactants concentrations that significantly lower than their CMC.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Covering: Up to end of June 2018 Baeyer-Villiger monooxygenases (BVMOs) are flavin-dependent enzymes that catalyse the oxidation of ketones and cyclic ketones to esters and lactones, respectively, by using molecular oxygen and NAD(P)H. BVMOs also catalyse sulfoxidations and N-oxidations. BVMOs are widely studied as attractive biocatalysts, but also catalyse key reactions in metabolic pathways of the organisms from which they are sourced. BVMOs are involved in the primary metabolism of atypical carbon sources, thereby conferring an evolutionary advantage to the host organism. In addition, BVMOs catalyse a plethora of diverse Baeyer-Villiger and heteroatom oxidations in the construction of complex secondary metabolites. These natural products often have attractive biological properties, such as anti-bacterial, anti-cancer and anti-proliferative activity, and can have clinical applications. In contrast, BVMOs are also involved in the synthesis of microbial toxins. This review will discuss the inherent roles of type I, type II and type O BVMOs in the metabolism of microorganisms.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Seven crystalline molecular complexes were formed between perfumes such as guaiacol, 2-methylindole, and skatole and cationic surfactants such as hexadecyl-, tetradecyl-, dodecyl-, and decyltrimethylammonium bromide from an aqueous or methanol solution at low temperatures (< 10 C). The crystal structures were determined by X-rays. The structures are very similar to each other, that is, the perfume molecules are packed in the layers of the alkyl chains of the surfactant molecules. Those packings are substantially the same as the common packing pattern observed in complexes between the surfactants and the aromatic compounds. The thermal analysis showed that the volatilization temperatures of the perfumes increased significantly when the perfumes are packed in the complex crystals. Moreover, the molar loss ratio of the perfume with increasing the temperature decreased with increasing the length of the alkyl chain of the surfactant. This suggests that thermal stability of the perfumes can be controlled by forming the complexes with the surfactants containing different alkyl chains. We’ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 1119-97-7, and how the biochemistry of the body works.Application of 1119-97-7

Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Measurements of the surface tension of aqueous solutions of Triton X-100, Triton X-114, Triton X-165, sodium dodecylsulfate, sodium hexadecylsulfonate, cetyltrimethylammonium bromide, cetylpyridinium bromide, sodium N-lauryl sarcosinate, dodecyldimethylethylammonium bromide, tetradecyltrimethylammonium bromide and benzyldimethyldodecylammonium bromide were made at different temperatures. On the basis of the obtained results the activity of the surfactants at the water-air interface was determined and discussed based on the intermolecular interactions. The surfactant activity at the water-air interface was taken into account for determination of thermodynamic parameters of surfactant adsorption using the Langmuir method and the Szyszkowski equation. The thermodynamic parameters were also determined by means of the Rosen and Aronson, Gamboa and Olea methods as well that based on the changes of tail-water interface tension to that of tail-air.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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High-resolution 13C CPMAS NMR spectra of anhydrous and of hydrated dipalmitoylphosphatidylcholine (DPPC) in gel-phase bilayers have been obtained.Judged from 13C NMR chemical shifts one can conclude that no substantial changes in the conformational equilibria of the acyl chains take place upon hydration, in contrast to conclusions drawn earlier from vibrational spectra.Incorporation n-tetradecyltrimethylammonium bromide in the bilayers does not cause conformational changes in the chains.Measurements of relaxation times in the rotating frame, T1p, both for 13C and 1H lead to the result that the mobilities on the 105 Hz time scale of the lecithin acyl chains and head groups are progressively decreased upon solubilization of more detergents.Opposite trends are found for the detergents.Those results are in agreement with previously published findings for, e.g., cholesterol solubilization in lipid bilayers, provided that one defines a cross-over region in the frequency domain at ca. 105 Hz.This view is supported strongly by the results of cross-polarization time (TCH) measurements.The previously postulated squeezing action of phospholipids on solubilized detergents in vesicles is shown to exist also in the gel phase.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Titanium phosphate containing long chain surfactants can be synthesized either by batch using the inorganic ion-exchanger gamma-titanium phosphate and surfactant solutions or via sol-gel by direct intercalation. The resulting content of the surfactants after being exchanged depends on the length of the chain and is greater in the case of the material obtained by direct intercalation. All of the material obtained has a layered structure and an increased interlayer distance. The longer the chain is the greater the increase in distance. The layered structure is maintained up to 300 C. The pyrophosphate formation occurs at 900 C in the case of material by direct intercalation, whereas in the case of batch material it occurs at a higher temperature. The surfactant loss occurs in three or more distinct stages. As far as the batch material is concerned the last loss occurs at a high temperature of ?800 C. Thermal treatment is carried out in air or nitrogen atmosphere for the better characterization of the processes.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Using tetradecyltrimethylammonium bromide (TTAB) as a surfactant denaturant, and augmentation of different spectroscopic data, helped to detect the intermediates of hemoglobin (Hb) during unfolding process. UV-vis, fluorescence, and circular dichroism spectroscopy were used simultaneously to monitor different aspects of hemoglobin species from the tertiary or secondary structure points of view. Application of the multivariate curve resolution-alternating least square (MCR-ALS), using the initial estimates of spectral profiles and appropriate constraints on different parts of augmented spectroscopic data, showed good efficiency for characterization of intermediates during Hb unfolding. These results indicated the existence of five protein species, including three intermediate-like compounds in this process. The unfolding pathway in the presence of TTAB included conversion of oxyhemoglobin into deoxyhemoglobin, and then ferrylhemoglobin, ferrihemoglobin or aquamethemoglobin, which finally transformed into hemichrome. This is the first application of chemometric analysis on the merged spectroscopic data related to chemical denaturation of a protein. These types of analysis in multisubunit proteins not only increase the domain of information, but also can reduce the ambiguities of the obtained results.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 1119-97-7 is helpful to your research. Recommanded Product: MitMAB

In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 1119-97-7, name is MitMAB, introducing its new discovery. Recommanded Product: MitMAB

Plateau borders (PBs) are liquid microchannels located at the contact between three bubbles in liquid foams. They are stable, deformable, and can be thought of as quasi-one-dimensional model systems to study surface waves in fluid dynamics. We show that the burst of a bubble trapped in a PB produces local constrictions which travel along the liquid channel at constant velocity, without significant change in shape. These patterns are reminiscent of the depression solitary waves encountered in nonlinear systems. By coupling flow inertia to capillary stresses, we derive a simple model that admits solitonic solutions, which we characterized numerically and analytically in the limit of small deformation. These solutions capture most of the features observed experimentally.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI