Reference of 148461-14-7, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 148461-14-7, Name is (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole, molecular formula is C24H24NOP. In a Article£¬once mentioned of 148461-14-7
Diastereoselective and Enantioselective Palladium-Catalyzed Allylic Substitution of Substituted Fluorinated Methylene Derivatives
The diastereoselective and enantioselective allylation of substituted monofluorinated methylene derivatives with diaryl-substituted allylic acetates was accomplished under Pd catalysis. This method gave fluorinated allyl products with two stereogenic centers in one pot. The dr values of these reactions were strongly governed by steric demand of the diaryl-substituted allylic acetates and the substituted fluorinated methylene derivatives. The application of the branched allyl products in the synthesis of fluorinated 3,4-dihydro-2H-pyrrole 1-oxide was also explored.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Reference of 148461-14-7, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 148461-14-7, in my other articles.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI