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Homo- and hetero-dinuclear nickel(II), copper(II), and oxidovanadium(IV) complexes of a Schiff-base-fused phthalocyanine (pc) with bulky substituents, 2,6-dimethylphenoxy and t-butyl groups, were prepared and characterized. The introduced salen-like Schiff-base unit was shown to affect the spectral feature based on the pc unit in the near infrared region, the Q band being widely split over 600-800 nm. A fairly large ferromagnetic interaction (J = 6.0 cm -1) was observed for the CuII(pc)-CuII(salen) homo-dinuclear complex, while an antiferromagnetic interaction (J = -3.2 cm -1) was observed for the CuII(pc)-VIVO(salen) hetero-dinuclear complex.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI