Top Picks: new discover of (S)-[1,1′-Binaphthalene]-2,2′-diol

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Related Products of 18531-99-2, you can also check out more blogs about18531-99-2

Related Products of 18531-99-2, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 18531-99-2, Name is (S)-[1,1′-Binaphthalene]-2,2′-diol, molecular formula is C20H14O2. In a Article,once mentioned of 18531-99-2

An economic and practical method for preparing enantiomerically pure [1,1?-binaphthalene]-2,2?-diols is reported. Thus, a condensate of threo-(1S,2S)-2-amino-1-(4-nitrophenyl)propane-1,3-diol and cyclohexanone (CHANP) was used as a resolving agent. A 2:1:1 mixture of racemic [1,1?-binaphthalene]-2,2?-diol, boric acid, and CHANP was refluxed for several hours in THF or MeCN to give a white precipitate of bis((R)-[1,1?-binaphthalene]-2,2?-diol}boric acid CHANP derivative, from the precipitate, and a filtrate separated from the precipitate, (R)- and (S)-[1,1?-binaphthalene]-2,2?-diol of 100% ee were obtained in ca. 65% yield, respectively.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Related Products of 18531-99-2, you can also check out more blogs about18531-99-2

Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI