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RuHCl(diphosphine)(diamine): Catalyst precursors for the stereoselective hydrogenation of ketones and imines

New chiral complexes RuHCl(diphosphine)(diamine) are readily prepared from RuHCl(PPH3)3. The diamine complexes, in the presence of alkoxide base, catalyze the hydrogenation of a wide variety of ketones and imines at 3 atm H2, 20C, including prochiral imines to chiral amines in good to excellent enantiomeric excess.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI