Chemistry is traditionally divided into organic and inorganic chemistry. Application In Synthesis of (1R,2R)-Cyclohexane-1,2-diamine. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 20439-47-8
Transition metal molecular glasses by design: Mexylaminotriazine-functionalized salicylaldehyde imine ligands
Mexylaminotriazines are a novel class of small molecules capable of forming stable glassy phases. When covalently linked to a variety of small molecules, mexylaminotriazines possess the ability to introduce resistance to crystallization and yield stable glassy phases for various other moieties that are traditionally unable to readily adopt glassy phases. To date, this has been applied particularly to opto-electronic devices. However, there is limited information regarding the synthesis of glass-forming metal complexes. Herein, a library of salicylaldehyde imine derivatives incorporating mexylaminotriazine substituents were synthesized, from which respective complexes with various first-row transition metals were prepared. The resulting compounds were characterized and evaluated for their glass-forming properties. It was found that all synthesized ligands and complexes demonstrated the ability to adopt glassy phases; however, the metal centre was identified as having a profound impact on the glass transition temperature (Tg). Additionally, it was found that the incorporation of mexylaminotriazine moieties to ligand frameworks may present a reliable and predictable strategy for the introduction of glass-forming properties into a variety of metal complexes.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Application In Synthesis of (1R,2R)-Cyclohexane-1,2-diamine, you can also check out more blogs about20439-47-8
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI