Related Products of 2926-30-9, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 2926-30-9, Name is Sodium trifluoromethanesulfonate, molecular formula is CF3NaO3S. In a Article£¬once mentioned of 2926-30-9
Novel catalytic hydrogenolysis of trimethylsilyl enol ethers by the use of an acidic ruthenium dihydrogen complex
The heterolytic cleavage of H2 is the key to the novel catalytic hydrogenolysis of trimethylsilyl enol ethers catalyzed by [RuCl(eta2- H2)(dppe)2]OTf (dppe = 1,2-bis(diphenylphosphanyl)ethane, OTf = trifluoromethanesulfonate), which results in the formation of a ketone and Me3SiH (see scheme). In addition, the stoichiometric, ruthenium-assisted protonation of a prochiral lithium enolate with H2 gave a chiral ketone with high enantioselectivity (up to 75 % ee).
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Related Products of 2926-30-9, you can also check out more blogs about2926-30-9
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI