Month: July 2021

Application of 18531-99-2, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.18531-99-2, Name is (S)-[1,1′-Binaphthalene]-2,2′-diol, molecular formula is C20H14O2. In a article，once mentioned of 18531-99-2

We report on a new class of P-O monophosphite ligands (designated 3a-k) with a double six-membered-ring backbone onto which are attached additional groups and on applications of their Rh complexes in the hydrogenation of enamides, alpha-dehydroamino acid esters, dimethyl itaconate, and beta-(acylamino)acrylates. Our results demonstrate that the Rh complexes with ligands 3a-k exhibit high enantioselectivity and reactivity in asymmetric hydrogenation reactions. An ee value of up to 98.0% was obtained for the hydrogenation of alpha-dehydroamino acid esters, and the ee values were all over 99% for the other three types of substrate, with a turnover number of up to 5000.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， Recommanded Product: 2,9-Dibromo-1,10-phenanthroline, Which mentioned a new discovery about 39069-02-8

The invention provides a nerve of surgical medicine temazepam intermediate compound of the formula (III) compound synthetic method, the synthetic method is as follows: in the catalyst, ligand, in the presence of alkali and accelerator, the following formula (I) compounds of the formula (II) compound in the organic solvent in the reaction, after-treatment after the reaction, so as to obtain states the type (III) compounds, the synthesis method through the unique reaction system, but can yield to obtain the target product. The invention also provides the above-mentioned compound recrystallization purification method, through the unique the re-crystallization method, can significantly improve the purity of the product, for the compound to provide new method for the purification of, and has good application prospect and potential. (by machine translation)

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Electric Literature of 4408-64-4, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.4408-64-4, Name is 2,2′-(Methylazanediyl)diacetic acid, molecular formula is C5H9NO4. In a article，once mentioned of 4408-64-4

Complexation behaviour of Cd with methylimino diacetic acid (MIDA) and some amino acids (alanine, glycine, aspartic and glutamic) have been investigated at DME. The formation of MXY, MXY2 and MX2Y complexes has been identified. The reduction of all these complexes has been found to be reversible and diffusion controlled, involving two electrons. The treatment of Schaap and McMasters has been used to evaluate the stability constants for all these complexes. The statistical and electrochemical effects have been discussed by using these stability constants. The positive values of mixing constants (KM) and stabilization constants (Ks) indicate that the ternary complexes are more stable than the binary complexes.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Application of 18511-69-8, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 18511-69-8, Name is [2,2′-Bipyridine]-4,4′-diamine, molecular formula is C10H10N4. In a Article，once mentioned of 18511-69-8

New ruthenium(II) photosensitizers [Ru(dcbpy)(L)(NCS)2] (dcbpy = 4,4?-dicarboxylic acid-2,2?-bipyridine; L = 4,4?-bis{di[4-(N,N?-dimethylamino)phenyl]amino}-2,2?-bipyridine (1), 4,4?-bis[di(4-methoxyphenyl)amino]-2,2?-bipyridine (2), and 4,4?-bis[di(4-tolyl)amino]-2,2?-bipyridine (3)) were prepared and characterized and their application in dye-sensitized solar cells is presented. The optical absorption of these photosensitizers gives a peak at around 540 nm, which is very similar to that of the standard N719. The maximum incident photon-to-current conversion efficiency (IPCE) of 80.6% was obtained for 3, which corresponded to a power conversion efficiency (eta) of 5.68% under standard air mass (AM) 1.5 sunlight (versus N719 at 6.76%). Molecular cosensitization of 3 with an organic dye, QS-DPP-I, yielded higher eta values up to 6% relative to the cells based on individual photosensitizers, and the corresponding IPCE can reach 93.6% at 549 nm. A preliminary stability test of the devices was also conducted.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Electric Literature of 1120-02-1, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1120-02-1, Name is OctMAB, molecular formula is C21H46BrN. In a Review，once mentioned of 1120-02-1

Selective oxidation has an important role in environmental and green chemistry (e.g., oxidative desulfurization of fuels and oxidative removal of mercury) as well as chemicals and intermediates chemistry to obtain high-value-added special products (e.g., organic sulfoxides and sulfones, aldehydes, ketones, carboxylic acids, epoxides, esters, and lactones). Due to their unique physical properties such as the nonvolatility, thermal stability, nonexplosion, high polarity, and temperature-dependent miscibility with water, ionic liquids (ILs) have attracted considerable attention as reaction solvents and media for selective oxidations and are considered as green alternatives to volatile organic solvents. Moreover, for easy separation and recyclable utilization, IL catalysts have attracted unprecedented attention as “biphasic catalyst” or “immobilized catalyst” by immobilizing metal- or nonmetal-containing ILs onto mineral or polymer supports to combine the unique properties of ILs (chemical and thermal stability, capacity for extraction of polar substrates and reaction products) with the extended surface of the supports. This review highlights the most recent outcomes on ILs in several important typical oxidation reactions. The contents are arranged in the series of oxidation of sulfides, oxidation of alcohols, epoxidation of alkenes, Baeyer-Villiger oxidation reaction, oxidation of alkanes, and oxidation of other compounds step by step involving ILs as solvents, catalysts, reagents, or their combinations.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Application of 123-46-6, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.123-46-6, Name is Girards Reagent T, molecular formula is C5H14ClN3O. In a Article，once mentioned of 123-46-6

Chemical ionization of organic compounds with negligible vapor pressures (VP) is achieved at atmospheric pressure when the proximal sample is exposed to corona discharge. The vapor-phase analyte is produced through a reactive olfaction process, which is determined to include electrostatic charge induction in the proximal condensed-phase sample, resulting in the liberation of free particles. With no requirement for physical contact, a new contained nano-atmospheric pressure chemical ionization (nAPCI) source was developed that allowed direct mass spectrometry analysis of complex mixtures at a sample consumption rate less than nmol/min. The contained nAPCI source was applied to analyze a wide range of samples including the detection of 1 ng/mL cocaine in serum and 200 pg/mL caffeine in raw urine, as well as the differentiation of chemical composition of perfumes and beverages. Polar (e.g., carminic acid; estimated VP 5.1 × 10-25 kPa) and nonpolar (e.g., vitamin D2; VP 8.5 × 10-11 kPa) compounds were successfully ionized by the contained nAPCI ion source under ambient conditions, with the corresponding ion types of 78 other organic compounds characterized.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 3030-47-5, molcular formula is C9H23N3, introducing its new discovery. SDS of cas: 3030-47-5

The structures of alkali metal complexes of silyl-substituted ansa-tris(allyl) ligands [RSi(C3H3SiMe3J 3]3- (R = Me, L1; or Ph, L2) are discussed, Triple deprotonation of L1H3 by nBuNa/tmeda affords [L1{Na(tmeda)}3] (4) in which the sodium cations are complexed by etan-allyl ligands and the silyl substituents adopt [exo,exo][endo,exo]2 stereochemistries in one crystallographically disordered form and [endo,exo]3 in another. Triple deprotonation of L2H3 with nBuLi/tmeda results in the formation of [L2{Li(tmeda)}3] (5), the structure of which features silyl substituents with [exo,exo]2[endo,exo] stereochemistries. The trisodium complex [L2Na{Na(tmeda)} 2]2 (6) consists of a hexa(allylsodium) macrocycle that aggregates as a result of cation-pi interactions between the phenyl substituents and the sodium cations. An attempt to prepare the tripotassium complex of L1 resulted in the formation of the bimetallic potassium/lithium, complex [L2{K(OEt2)2} 2KL1(mu4-OtBu)]2 (7), in which the lithium tertbutoxide by-product is incorporated into a hexa(allylpotassium) macrocycle. Triple deprotonation of L1H3 with nBuLi and the terdentate Lewis base pmdeta results in [L1Li(pmdeta)}3] (8), in which the three allyl groups do not mubridge between lithium cations, resulting in an [exo,exo]3 stereochemistry of the silyl substituents, NMR spectroscopic studies reveal complicated solution-phase behaviour for 4, 6 and 7, whereas the solid-state structures of 5 and 8 are preserved in solution. Further insight into the structures and stereochemical preference of the ansa-tris (allyl) ligands in 4 and 5 is provided by detailed density functional theory calculations.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， SDS of cas: 3153-26-2, Which mentioned a new discovery about 3153-26-2

In this study we have examined the catalytic activity of vanadium(V) complexes such as left bracket VO(DBcat**)//2 right bracket ** minus and heteropolyvanadates for the purpose of comparison with the previous results. In particular, we have interested in oxygenation using heteropolyvanadates because these compounds have polynuclear structures with many oxyanions capable of oxidizing organic compounds. The authors discuss the reaction mechanism on the basis of the isolated complex which can be regarded as an intermediate of the reaction.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Application of 448-61-3, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 448-61-3, Name is 2,4,6-Triphenylpyrylium tetrafluoroborate, molecular formula is C23H17BF4O. In a Article，once mentioned of 448-61-3

A Suzuki-Miyaura cross-coupling of alpha-pyridinium esters and arylboroxines has been developed. Combined with formation of the pyridinium salts from amino acid derivatives, this method enables amino acid derivatives to be efficiently transformed into alpha-aryl esters and amides. Under the mild conditions, broad functional group tolerance on both the amino acid derivatives and the arylboroxine are observed, including protic functional groups. Mechanistic studies support an alkyl radical intermediate, similar to other cross-couplings of alkylpyridinium salts.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, name: [2,2′-Bipyridine]-4,4′-diamine, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 18511-69-8, Name is [2,2′-Bipyridine]-4,4′-diamine, molecular formula is C10H10N4. In a Article, authors is Guo, Lihua，once mentioned of 18511-69-8

The synthesis and characterization of a series of organometallic half-sandwich N,N-chelated iridium(iii) complexes bearing a range of electron-donating and withdrawing substituents were described. The X-ray crystal structures of complexes 1, 3 and 5 have been determined. This work demonstrated how the aqueous chemistry, catalytic activity in converting coenzyme NADH to NAD+ and anticancer activity can be controlled and fine-tuned by the modification of the ligand electronic perturbations. In general, the introduction of an electron-withdrawing group (-Cl and-NO2) on the bipyridine ring resulted in increased anticancer activity, whereas an electron-donating group (-NH2,-OH and-OCH3) decreased the anticancer activity. Complex 6 bearing a strongly electron-withdrawing NO2 group displayed the highest anticancer activity (7.3 ± 1.2 muM), ca. three times as active as cisplatin in the A549 cell line. Notably, selective cytotoxicity for cancer cells over normal cells was observed for complexes 1 and 6. DNA binding does not seem to be the primary mechanism for cancer fighting. However, the aqueous chemistry, cell apoptosis and cell cycle, which show similar dependence on the ligand electronic perturbations as the anticancer activity, appear to together contribute to the anticancer potency of theses complexes. This work may provide an alternative strategy to enhance anticancer activity for these N,N-chelated organometallic half-sandwich iridium(iii) complexes.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI