08/9/2021 News Extracurricular laboratory:new discovery of 94928-86-6

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Electric Literature of 94928-86-6, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.94928-86-6, Name is fac-Tris(2-phenylpyridine)iridium, molecular formula is C33H27IrN3. In a Article,once mentioned of 94928-86-6

A visible-light-promoted C(sp3)-H amidation and chlorination of N-chlorosulfonamides (NCSs) is reported. This remote C(sp3)-H functionalization can be achieved in weak basic solution at room temperature with as little as 0.1 mol % of a photocatalyst. A variety of nitrogen-containing heterocycles (up to 94% yield) and chlorides (up to 93% yield) are prepared from NCSs. Late-stage C(sp3)-H functionalization of complex and biologically important (-)-cis-myrtanylamine and (+)-dehydroabietylamine derivatives can also be achieved with excellent yields and regioselectivity.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI